Collections, and most other iterables, can be unpacked into individual names, by assigning the collection to a comma-separated list of names.

composers = ['Dvorak', 'Tian', 'Richter', 'Beethoven', 'Holst', 'Elgar']

first, second, third, fourth, fifth, sixth = composers
print(first)  # prints 'Dvorak'
print(second)  # prints 'Tian'
print(third)  # prints 'Richter'
print(fourth)  # prints 'Beethoven'
print(fifth)  # prints 'Holst'
print(sixth)  # prints 'Elgar'

There must be enough names on the left side of the assignment operator to hold all the values. Otherwise, a ValueError is raised.

A single starred expression, a name preceded with an asterisk, may be used in the list of names to capture multiple values.

first, second, third, *rest = composers
print(first)  # prints 'Dvorak'
print(second)  # prints 'Tian'
print(third)  # prints 'Richter'
print(rest)  # prints ['Beethoven', 'Holst', 'Elgar']

All of the non-starred names will be assigned to first, and the remainder placed in the starred name.

The name _ is conventionally used for values that are being ignored.

first, _, _, _, _, last = composers
print(first)  # prints 'Dvorak'
print(last)  # prints 'Elgar'

Like any name, _ can also be starred:

first, *_, last = composers
print(first)  # prints 'Dvorak'
print(last)  # prints 'Elgar'

Unpacking is also employed in for loops, generator expressions, and argument lists. Anywhere an iterable is being assigned, unpacking can be used.

CAUTION: Do not attempt to unpack an infinite iterator using starred expressions. It can cause the interpreter (or even the whole system) to lock up.